Spectroscopy: Detect absorption spectra of gemstones

Spectroscopes can be used to generate characteristic absorption spectra of colored stones. These absorption spectra are almost like individual fingerprints which allow many stones to be determined or stones of the same colour to be separated quickly and reliably. Transparent or translucent stones in their rough or polished state are suitable for this type of investigation. It may also be possible to observe the spectra of opaque stones by using the light reflected from the surface. In the case gemstones of different colours, various absorptions take place, for which the respective individual chemical compositions and crystal structures are responsible. These absorptions determine the chromaticity of the stones at the same time. Naturally, only clearly colored stones produce an absorption spectrum, as there is no absorption in colourless stones and pale-colored stones do not absorb sufficiently for a clearly visible spectrum.

Function spectroscope

The spectroscope has a narrow slit for for light entry or light incidence, in front of which a stone is placed. If the stone is illuminated by light, a certain part of the light is absorbed by the stone. The other part is broken down into its absorption spectrum inside the spectroscope and is visible to the observer in the eyepiece.

Spectroscopy: Absorption spectra of coloured stones

Dark lines and stripes appear where certain wavelengths are absorbed by the stone. This produces an absorption spectrum, which is visible to the observer in the eyepiece. By fading in the wavelength scale, absorption lines can be measured directly. Reference spectra for the most common gemstones and precious stones are listed and illustrated in the gemmological literature. An example are the Fraunhofer lines and absorption bands (right figure).

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More Information

Do you want to read more?

If you are looking for more specialist information, order the white paper “Gemstone Spectroscopy”. The following topics, for example, are described in the specialist publication:

  • Structure and mode of operation of a Spectroscopes
  • Spectral colours, produced by refraction of white light
  • The visible spectrum for humans
  • Comparison of the absorption spectra of red gemstones
  • How do spectra of colours come into existence?
  • Practical tips: Spectroscope investigation
  • Extract of colour chart Fraunhofer’s lines and absorption bands
  • Spectra of ruby, red spinel, garnet, almandine, alexandrite, red tourmaline

The whitepaper was produced in collaboration with Prof. Dr. Jochen Schlueter wrote. a qualified mineralogist in charge of the permanent collection on display at the Mineralogical Museum in Hamburg.

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